Informing Spectroscopists for Over 40 Years

Sampling Columns

Editor: Kim H. Esbensen

What is the meaning of analysing any sample if it cannot be documented to be representative? The answer is “none”, and that is the reason for this column. Starting with the Theory of Sampling, it builds into a valuable resource covering the theory and practice of representative sampling.
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In the Sampling Column, Kim Esbensen and Claas Wagner continue our education about representative sampling. In “Sampling quality assessment: the replication experiment”, they provide an overview of the issue of replication, which may not be as straightforward as might be expected at first.

Issue 28/1 (2016)

Kim Esbensen and Claas Wagner’s Sampling Column also addresses issues around ensuring valid results, from the sampling perspective. “Composite sampling II: lot dimensionality transformation” continues to address the problem of heterogeneity and how to overcome it. If you can find a time when your bulk (3D) sample becomes a 1D sample, the job is possible. Interesting examples from unloading a grain ship to emptying a fishing boat hold are described.

Issue 27/6 (2015)

Kim Esbensen and Claas Wagner tackle the problem of heterogeneity in sampling and show how it can be dealt with at the primary sampling stage by “Composite sampling I: the Fundamental Sampling Principle”. As well as explaining the theory they also introduce practical solutions. Kim Esbensen and Claas Wagner tackle the problem of heterogeneity in sampling and show how it can be dealt with at the primary sampling stage by “Composite sampling I: the Fundamental Sampling Principle”. As well as explaining the theory they also introduce practical solutions.

Issue 27/5 (2015)

Kim Esbensen and Claas Wagner have gold on their minds. However, only to explain that “Sampling—is not gambling!”: the American “Gold Rush” of the late 19th Century is a good metaphor for the unrepresentative nature of grab sampling: something that you will soon realise is to be avoided in any sampling regime.

Issue 27/4 (2015)

Kim Esbensen and Claas Wagner continue their study of “Heterogeneity—the root of all evil” in the Sampling Column. We would be most interested to hear readers’ views on our new column. Representative sampling is essential for most analyses to be relevant, and the column will move from its early theoretical introduction to practical solutions. Readers interested in learning more about the Theory of Sampling may be interested in the Proceedings of the 7th World Conference on Sampling and Blending which are now freely available at http://www.impublications.com/wcsb7.

Issue 27/3 (2015)

In the new Sampling Column, Kim Esbensen and Claas Wagner tell us about hetergeneity and why it is everywhere and should always be considered when sampling. The next issue will see a second part looking at how to avoid the errors involved in sampling heterogeneous materials—and that is all of them!

Issue 27/2 (2015)

Further introduction to the Theory of Sampling by Kim Esbensen and Claas Wagner

Issue 27/1 (2015)

This is a new column on Sampling, edited by Kim Esbensen and Claas Wagner. I really only became aware of the Theory of Sampling (TOS) following conversations with Kim at the NIR-2013 conference in La Grande Motte, near Montpellier, France. I won’t steal Kim and Claas’ thunder by going into detail, but I see this new column as a perfect complement to our others. Ian Michael, editor.

Issue 26/6 (2014)

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